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Asha� Article |
Asha� Scientific Article |
Therefore, you have to take other factors into
account to assess durability
of a simulant. While
moissanite is the hardest of diamond simulants on
the
mohs scale (averaging at 9.25), it is also quite
susceptible to chipping as
many jewelers and owners
have discovered. This is probably why chipping is
not covered in the Moissanite limited warranty.
CZ based simulants will vary both in their Mohs
rating and toughness rating.
Asha� rates at 8.5+, as
do many other formulations, while other CZ's will
rate at 8.0. Toughness is difficult to measure per
se, but our scientist did
find that our Asha�
version3 proved much more difficult to shatter via
hammer blows than any other Asha� versions or other
CZ simulants they
had tested. As a result of the v3
toughness improvement, Asha� now
warrants against
chipping and fracturing under normal daily wear.
Retention of optical properties
While CZ simulants are generally the closest optical
clones of a diamond,
one thing that has made them
the bane of most self-respecting jewelry
owners is
their notorious habit of changing color over time.
Thus, many
customers who thought they were getting a
good deal buying a cheap CZ
soon found out six
months later they just had a plastic looking blob in
their ring.
Since cheap CZ is just that, cheap, most
manufacturers/jewelers dealing
in CZ simply took the
approach of "just keep replacing the cz every year",
or else only mount it in cheap, throw-away type of
jewelry. This in part is
what greatly damaged the
reputation of CZ in most consumers eyes.
Thus, there was not much financial interest for
anyone associated with CZ
simulants to actually do
any scientific research into trying to understand
what caused color changes or clouding in CZ. For
Asha�, we took the
opposite tact, that of trying to
understand why and have made a lot of
progress on
understanding why CZ changes color, and currently
have a
very good working theory as to the molecular
changes that cause the color
to change. Since we
funded this work on our own, it will not be
published as
we originally intended, but is part of
the reason we warrant Asha� for the
lifetime of the
owner against color change. Of interest/humor was
the
number of reasons that were 'told' to us by
people in the jewelry industry
about why many/most cz's don't hold their color, which proved to be
completely groundless in scientific testing.
"A CZ is just a CZ"...right?
Only if "cubic carbon is just cubic carbon", yet as
you know 'cubic carbon'
is diamond, and diamonds can
vary widely in appearance, desirability, and
cost.
CZ is a shortened form of the term 'cubic zirconia',
and comes from
the fact that many diamond simulants
place an oxide of the metallic element
zirconium
into a forced but stabilized cubic structure.
However, that's all the
term addresses. Beyond that,
the term cubic zirconia simply defines a range
of
crystal recipes that can distort and change the
physical and optical
properties of the zirconia unit
cell, altering both optical and physical
characteristics as well as electrical conductivity.
For example, beyond the fact that zirconium is now
in a cubic structure, all
other bets are off. To
keep the zirconium in its cubic state, you have to
add
what is termed a dopant - this is an element
that will fill the missing holes
within the cubic
unit cell in order to ensure it stays cubic at room
temperature. Dopant materials can include yttrium
(YO2), calcium (CaOx),
MnOx, TiO2, etc. and just
like adding different ingredients to a recipe, you
can then produce a different end-result.
Chocolate makes a good analogy - all chocolate has
at its core cocoa. But
few people will refuse to
make further distinctions based on additional
ingredients, purity of the ingredients, proportions
of the ingredients, etc.
which is why it's surprising
to often see such simplistic thinking applied to
CZ-based simulants.
Also of interest - most jewelers will tell you that
cubic zirconia is a man-
made only gem. This, in
fact, is not correct (check with the GIA), and the
proper full name is legally "synthetic cubic zirconia". The synthetic indicates
that it is the
man-made equivalent of a natural gem. Natural
cubic-zirconia
does exist, in extremely rare
conditions in nature. However, because of its
rarity, the synthetic adjective is usually
dropped.
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